Rovibrational quantum state resolution of the C60 fullerene

The unique physical properties of buckminsterfullerene, C₆₀, have attracted intense research activity since its original discovery. Total quantum state-resolved spectroscopy of isolated C₆₀ molecules has been of particularly long-standing interest. Such observations have, to date, been unsuccessful owing to the difficulty in preparing cold, gas-phase C₆₀ in sufficiently high densities. Here we report high-resolution infrared absorption spectroscopy of C₆₀ in the 8.5-micron spectral region (1180 to 1190 wave number).