Supramolecular chemistry and materials at very high pressures

Supramolecular chemistry and materials at very high pressures figure.

Artistic rendition of perovskite nanocrystals in a diamond anvil cell.

Image Credit
Steven Burrows

Nanostructured materials (quantum dots, nanowires, nanocrystals) have led to a large research field in the last two decades. While there is a huge body of work on their synthesis, the molecular-level details of their interactions with their chemical environment is only beginning to be explored. High pressure experiments offer access to tackle such questions.

At relatively low pressures (a few hundred MPa), only intermolecular distances are varied by application of pressure. This is much less perturbative than variation of temperature or chemical composition. The behavior of nanocrystals at these low pressures yields information on the properties of the interface between thenanocrystals and their chemical environment, including their protective ligands. Higher pressures (GPa range) can result in phase changes in the solvent or in the nanocrystals themselves. The former will again lead to a change in the interaction of the nanocrystal with its environment. The latter affords access to new materials with new optical and electronic properties.
We use photoluminescence spectroscopy and Raman microspectroscopy to study these phenomena, employing a diamond anvil cell and a hydraulic cell to subject samples to high pressure. Learn about some of our work here and here. This work is supported by the NSF through the JILA Physics Frontier Center.