TY - JOUR
AU - Thinh Bui
AU - Bryan Changala
AU - Bryce Bjork
AU - Qi Yu
AU - Yimin Wang
AU - John Stanton
AU - Joel Bowman
AU - Jun Ye
AB - We use time-resolved direct frequency comb spectroscopy in the mid-infrared to obtain high-resolution rovibrational spectra of products produced from the OD + CO reaction. In this work, we present spectral analyses for isotopologues of the transient DOCO radicals from this reaction in the OD stretch region. The analyses were performed with the aid of two different theoretical approaches based on both perturbation theory and variational calculations used for prediction of rovibrational spectra of polyatomic molecules. We discuss the advantages and challenges of our current approach for studying spectroscopy and dynamics of transient molecules.
BT - Molecular Physics
DA - 2018-06
DO - 10.1080/00268976.2018.1484949
N2 - We use time-resolved direct frequency comb spectroscopy in the mid-infrared to obtain high-resolution rovibrational spectra of products produced from the OD + CO reaction. In this work, we present spectral analyses for isotopologues of the transient DOCO radicals from this reaction in the OD stretch region. The analyses were performed with the aid of two different theoretical approaches based on both perturbation theory and variational calculations used for prediction of rovibrational spectra of polyatomic molecules. We discuss the advantages and challenges of our current approach for studying spectroscopy and dynamics of transient molecules.
PY - 2018
SP - 1
EP - 8
T2 - Molecular Physics
TI - Spectral analyses of trans- and cis-DOCO transients via comb spectroscopy
SN - 0026-8976
ER -