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Interactions of Molecular Titanium Oxides TiOx (x=1-3) with Carbon Dioxide in Cluster Anions

TitleInteractions of Molecular Titanium Oxides TiOx (x=1-3) with Carbon Dioxide in Cluster Anions
Publication TypeJournal Article
Year of Publication2018
AuthorsDodson, LG, Thompson, MC, J. Weber, M
JournalThe Journal of Physical Chemistry A
Volume122
Issue34
Pagination6909 - 6917
Date Published2018-08
ISSN1089-5639
Abstract

We study small titanium oxide–CO2 cluster anions in vacuo to understand the fundamental interactions between TiOx and CO2 in the presence of an excess electron. Infrared spectra of [TiOx(CO2)y] (x = 1–3, y > 1) were obtained using photodissociation spectroscopy and assigned through quantum chemistry calculations, identifying the formation of carbonato, oxalato, oxo, η2-(O,O), and carbonyl ligands in the core ions of these clusters, with carbonato ligands being the dominant ligand species.

URLhttps://pubs.acs.org/doi/pdfplus/10.1021/acs.jpca.8b06229
DOI10.1021/acs.jpca.8b06229

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