High Resolution Laser Spectroscopy of Radicals, Ions, and Molecular Ion Clusters

Recent Papers in these Areas:

E. Sharp-Williams, M. A. Roberts, and D. J. Nesbitt, “High resolution slit-jet infrared spectroscopy of ethynyl radical: 2P-2S+ vibronic bands with sub-Doppler resolution,” J. Chem. Phys. 134, 064314 (2011).

C. Savage, F. Dong and D. J. Nesbitt, “High resolution spectroscopy of jet cooled CH5+: Progress,” American Institute of Physics, Proceedings International Conference of Computational Methods in Sciences and Engineering (in press).

A. van der Avoird and D. J. Nesbitt, “Rovibrational states of the H2O-H2 complex: An ab initio calculation,” J. Chem. Phys 134, 044314 (2011).

A. van der Avoird, Y. Scribano, A. Faure,  M. J. Weida,  J. R. Fair,  and D. J. Nesbitt, “Intermolecular potential and rovibrational states of the H2O-D2 complex,” Chem. Phys. 399, 28-38 (2012).

A. R. Sharma, J. M. Bowman, D. J. Nesbitt, “Large-amplitude dynamics in vinyl radical: The role of quantum tunneling as an isomerization mechanism,” J. Chem. Phys. 136, 034305 (2012).

M. A. Roberts, C. Savage, F. Dong, E. N. Sharp-Williams, A. B. McCoy, and D. J. Nesbitt, “Sub-Doppler Infrared Spectroscopy of CH2D Radical in a Slit Supersonic Jet: Isotopic Symmetry Breaking in the C-H Stretching Manifold,” J. Chem. Phys. 136, 234308 (2012).

M. P. Ziemkiewicz, C. Pluetzer, D. J. Nesbitt, Y. Scribano, A. Faure, A. van der Avoird, “Overtone vibrational spectroscopy in H2-H2O complexes: A combined high level theoretical ab initio, dynamical and experimental study,” J. Chem. Phys. 137, 084301 (2012).

D. J. Nesbitt, “Toward state-to-state dynamics in ultracold collisions: Lessons from high resolution spectroscopy of weakly bound molecular complexes,” Chem. Rev. dx.doi.org/10.1021/cr300208b (2012).

 M. A. Roberts, E. N. Sharp-Williams and D. J. Nesbitt, “High-resolution direct-absorption spectroscopy of hydroxymethyl radical in the CH symmetric stretching region,” J. Phys. Chem. A 117 , 7042-7049   DOI: 10.1021/jp312877k (2013)

G. T. Buckingham, C.-H. Chang and D. J. Nesbitt, “High-resolution rovibrational spectroscopy of jet-cooled phenyl radical: The ν19 out-of-phase symmetric CH stretch,”J. Phys. Chem. A. 117, 10047-10057 DOI: 10.1021/jp400702p (2013).

C.-H. Chang, G. T. Buckingham and D. J. Nesbitt, “Sub-Doppler spectroscopy of trans-HOCO radical in the OH stretching mode,” J. Phys. Chem. A, 117, 13255-13264 DOI: 10.1021/jp403386d (2013).

C. - H. Chang and Nesbitt, D. J. , Spectroscopy and dynamics of jet cooled polyynes in a slip supersonic discharge: Sub-Doppler infrared spectroscopy of diaacetylene HCCCCH, The Journal of Physical Chemistry A, vol. 119, no. 28, pp. 7940–7950, 2015.

K. T. Early and Nesbitt, D. J. , Two-Photon Excited Fluorescence Intermittency in Single CdSe/ZnS Quantum Dots, Nano Letters, vol. 15, no. 12, pp. 7781–7787, 2015.

C. - H. Chang, Agarwal, J. , Allen, W. D. , and Nesbitt, D. J. , Sub-Doppler infrared spectroscopy and reaction dynamics of triacetylene in a slit supersonic expansion, The Journal of Chemical Physics, vol. 144, 2016.

C. - H. Chang and Nesbitt, D. J. , High resolution spectroscopy of jet cooled phenyl radical: The v1 and V2 symmetry C-H stretching modes, Journal of Chemical Physics, vol. 145, 2016.